Narayani was born on 16th April 1978 in Pune, Maharashtra, India. She completed her education from Symbiosis College in Pune. Later she joined Government Law College in Mumbai. She entered in Indian television drama “Kahani Saat Phero Ki”, aired on D.D national. She got a chance to play a lead role in the television serial names “ Piya Ka Ghar”, aired on Zee Television. Her character name was “Rimjhim”. Later she worked in “ Mamta” by replacing Neha Mehta, who played a lead character on that show.

She again gets a chance to act in very famous television serial “ Kyunki Saas Bhi Kabhi Bahu Thi”, aired on Star Plus. She played a character of tulsi’s (played by Smriti Irani) sister “ Kesar”. She acted in many television shows like Kohi Apna sa aired on Zee T.V, Ghar Ki Lakshmi Betiyann, Twinkle Beauty Parlour in Sab T.V, Namak Haram, Phir Subah Hogi and many more. She worked in serial named “ Kkusum” where she plays a character of a vamp named Tashu, an Abhay evil wife. She participated in dance reality show “Zara Nachke Dikha”, air on Star One and also participated in reality show “ Meethi Choori No 1”.

She puts her legs in silver screen by choosing supporting role in movie “Chandni Bar”, Na Ghar Ke Na Ghat Ke and Pak Pak Pakkak.