Devyani is broadcasted on 19th March 2012 on Star Pravah. This show is going to replace ‘Bandh Reshmanche'. The story of the serial around the girl named ‘Devyani' a college-going girl whose life gets changed after she enters the wedlock with her obsessive and die-hard lover Sangram Vikhe Patil. Devyani is a girl of her principles that are taught by his father, Sangram is opposite and who always follows his principles in life and is the master of his decisions.
The show takes a new turn when Sangram falls head over heels with Devyani and makes all his efforts to let the girl become his wife. In the next instance, her marriage is arranged with a boy named Dr. Namit. What happens next and how will Sangram manages to get the love of his wife forms the premise of the show.